RESUMO
Mineral inclusions in diamonds provide an important source of information about the composition of the continental lithosphere at depths exceeding 120-150 km, i.e., within the diamond stability field. Fossilized high pressures in coesite inclusions from a Venezuela diamond have been identified and measured by using laser Raman and synchrotron x-ray microanalytical techniques. Micro-Raman measurements on an intact inclusion of remnant vibrational band shifts give a high confining pressure of 3.62 (+/-0.18) GPa. Synchrotron single-crystal diffraction measurements of the volume compression are in accord with the Raman results and also revealed direct structural information on the state of the inclusion. In contrast to olivine and garnet inclusions, the thermoelasticity of coesite favors accurate identification of pressure preservation. Owing to the unique combination of physical properties of coesite and diamond, this "coesite-in-diamond" geobarometer is virtually independent of temperature, allowing an estimation of the initial pressure of Venezuela diamond formation of 5.5 (+/-0.5) GPa.
RESUMO
An olivine nephelinite from the lower part of a thick alkalic ultrabasic and mafic sequence of volcanic rocks of the northeastern part of the Siberian flood basalt province (SFBP) yielded a (40)Ar/(39)Ar plateau age of 253.3 +/- 2.6 million years, distinctly older than the main tholeiitic pulse of the SFBP at 250.0 million years. Olivine phenocrysts of this rock showed (3)He/(4)He ratios up to 12.7 times the atmospheric ratio; these values suggest a lower mantle plume origin. The neodymium and strontium isotopes, rare earth element concentration patterns, and cerium/lead ratios of the associated rocks were also consistent with their derivation from a near-chondritic, primitive plume. Geochemical data from the 250-million-year-old volcanic rocks higher up in the sequence indicate interaction of this high-(3)He SFBP plume with a suboceanic-type upper mantle beneath Siberia.
